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Preparation of Novel Dendrimeric Hyperbranched Polymer-GdO Composites Loaded With Sphingosine Inhibitor-I/II.

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Chemistry & biodiversity 📖 저널 OA 14.7% 2021: 0/1 OA 2024: 0/1 OA 2025: 6/32 OA 2026: 10/75 OA 2021~2026 2026 Vol.23(3) p. e02899
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Kutlu E, Emen FM, Ali MA, Kutlu HM, Sezer CV

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Functionalized dendrimeric nanoparticles (BH40-PEG-F127-FA) were synthesized to develop a targeted delivery platform for combined therapeutic and imaging applications.

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APA Kutlu E, Emen FM, et al. (2026). Preparation of Novel Dendrimeric Hyperbranched Polymer-GdO Composites Loaded With Sphingosine Inhibitor-I/II.. Chemistry & biodiversity, 23(3), e02899. https://doi.org/10.1002/cbdv.202502899
MLA Kutlu E, et al.. "Preparation of Novel Dendrimeric Hyperbranched Polymer-GdO Composites Loaded With Sphingosine Inhibitor-I/II.." Chemistry & biodiversity, vol. 23, no. 3, 2026, pp. e02899.
PMID 41872670 ↗

Abstract

Functionalized dendrimeric nanoparticles (BH40-PEG-F127-FA) were synthesized to develop a targeted delivery platform for combined therapeutic and imaging applications. Structural confirmation through FT-IR, H-NMR, C-NMR, and MALDI-TOF mass spectrometry verified the successful formation of the macromolecular architecture. The nanoparticles exhibited hydrodynamic sizes of 190-255 nm, while transmission electron microscopy revealed micellar structures ranging from 35 to 190 nm. The critical micelle concentration of the copolymer was determined as approximately 0.001 mg/mL. Thermal analyses demonstrated the stability of BH40-PEG and BH40-PEG-F127-FA. GdO and sphingosine kinase inhibitors (SKI-I/II) were incorporated using a supercritical CO method, and structural integrity after loading was confirmed by FT-IR and x-ray diffraction. Drug-release studies performed in phosphate-buffered saline (pH 6.7, 37°C) indicated a sustained release over 192 h. Cytotoxicity assays on A549 lung cancer cells and Beas-2B healthy epithelial cells revealed selective antiproliferative activity, while confocal microscopy demonstrated treatment-induced morphological alterations. Overall, BH40-PEG-F127-FA nanoparticles show strong potential as biocompatible carriers for targeted therapy and multimodal imaging.

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